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- W2237263833 abstract "Vinyl sulfides represent an important class of compounds in organic chemistry and materials science. Atom-economic addition of thiols to the triple bond of alkynes provides an excellent opportunity for environmentally friendly processes. We have found that well-known and readily available Pd-NHC complex (IMes)Pd(acac)Cl is an efficient catalyst for alkyne hydrothiolation. The reported technique provides a general one-pot approach for the selective preparation of Markovnikov-type vinyl sulfides starting from tertiary, secondary, or primary aliphatic thiols, as well as benzylic and aromatic thiols. In all the studied cases, the products were formed in excellent selectivity and good yields." @default.
- W2237263833 created "2016-06-24" @default.
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- W2237263833 date "2015-11-09" @default.
- W2237263833 modified "2023-10-18" @default.
- W2237263833 title "Pd-NHC Catalytic System for the Efficient Atom-Economic Synthesis of Vinyl Sulfides from Tertiary, Secondary, or Primary Thiols" @default.
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- W2237263833 doi "https://doi.org/10.1021/acscatal.5b01815" @default.
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