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• W2237494818 abstract "An acylated anthocyanin trioside was isolated from pink flowers of Convolvulus althaeoides using a combination of chromatographic techniques. On the basis of MS (MALDI-TOF) and NMR (1H NMR, 1H-1H COSY, 1D TOCSY, HSQC, HMBC, 13C CAPT) its structure was determined as cyanidin 3-O-[6-O-(4-O- (6-O-(E-caffeoyl)-β-D-glucopyranosyl)-β-L-rhamnopyranosyl)-β-D-glucopyranoside]-5-O-β-D-glucopyranoside. The absolute configuration of the aldose enantiomer moieties was determined from the separation of the corresponding thiazolidine diastereoisomer derivatives by HPLC-DAD. This is a novel trisaccharide within the flavonoids, and the first complete characterization of a linear glucosyl-rhamnosyl-glucoside (4'-glucosylrutinoside) within the anthocyanins. Whilst acylation of rhamnose moieties in position 4 is quite common, the occurrence in anthocyanins of a glycosylated rhamnose is a unique trait. Although many complex anthocyanins have been found amongst the Convolvulaceae, the genus Convolvulus had not yet been surveyed for anthocyanins and thus this account could be of significance within the current chemotaxonomy of this family." @default.
• W2237494818 created "2016-06-24" @default.
• W2237494818 creator A5001399325 @default.
• W2237494818 date "2015-11-01" @default.
• W2237494818 modified "2023-09-25" @default.
• W2237494818 title "A Novel Acylated Anthocyanin with a Linear Trisaccharide from Flowers of <i>Convolvulus althaeoides</i>" @default.
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• W2237494818 doi "https://doi.org/10.1177/1934578x1501001140" @default.
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