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- W2237588051 abstract "We report the magnetic, electronic, and structural properties of nano-composite (Co84Zr16)Nx or CZN films prepared by reactive co-sputter deposition method. As-deposited CZN films have shown enhancement in magnetization (Ms) with incorporation of nitrogen content, which is related to the evolution of nano-composite phase. X-ray diffraction study has confirmed poly-crystalline growth of CZN films with fcc(331) and fcc(422) phases. High-resolution transmission electron microscope study reveals that CZN films are composed of ordered and crystalline ferromagnetic Co nano-clusters, which are embedded in the nano-composite matrix. Photoemission measurements show the change in the intensity near the Fermi level most likely due to defects and shift in the core-levels binding energy with nitrogen concentration. Raman spectroscopy data show an increase in the intensity of the Raman lines with nitrogen concentration upto 20%. However, the intensity is significantly lower for 30% sample. This indicates that less nitrogen or defect states are being substituted into the lattice above 20% and is consistent with the observed magnetic behavior. Our studies indicate that defects induced due to the incorporation of non-magnetic nitrogen content play a key role to enhance the magnetization." @default.
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- W2237588051 date "2016-01-01" @default.
- W2237588051 modified "2023-09-26" @default.
- W2237588051 title "Magnetization enhancement due to incorporation of non-magnetic nitrogen content in (Co84Zr16)Nxnano-composite films" @default.
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- W2237588051 doi "https://doi.org/10.1063/1.4939937" @default.
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