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- W2237850315 abstract "The fluoride method of zeolite synthesis yields materials with unique characteristics such as high Si/Al ratio, large crystal size, and hydrophobic properties, and it has been advantageous for the synthesis of new pure-silica or high-silica zeolites. It is often difficult, however, to incorporate aluminum—and thus bring about useful catalytic properties—in materials prepared through the fluorite method. In this report, we show that FAU-type zeolites are an effective source of aluminum to the growing crystals in the high-silica LTA-type zeolite synthesis (ITQ-29). A key advantage of using aluminosilicate zeolite crystals as aluminum source in fluoride media was the high reproducibility and easy control of the Si/Al ratio of the product. The broad applicability of this methodology was demonstrated in the synthesis of several high-silica zeolites in fluoride media: we report the synthesis of aluminosilicate ITQ-12 (ITW-type zeolite). Other more conventional aluminosilicate zeolites (CHA-, *BEA-, and STT-type..." @default.
- W2237850315 created "2016-06-24" @default.
- W2237850315 creator A5039313369 @default.
- W2237850315 creator A5084257483 @default.
- W2237850315 date "2016-01-13" @default.
- W2237850315 modified "2023-09-26" @default.
- W2237850315 title "A General Method for Aluminum Incorporation into High-Silica Zeolites Prepared in Fluoride Media" @default.
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- W2237850315 doi "https://doi.org/10.1021/acs.chemmater.5b04439" @default.
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