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- W2238024636 abstract "A new ultraviolet nonlinear optical (NLO) material, Pb3Mg3TeP2O14 (PMTP), has been synthesized and characterized. The chiral material exhibits a large second harmonic generation (SHG) response of 13.5 × KDP (600 × α-SiO2), and the shortest absorption edge (250 nm) of reported materials with a strong SHG response (>10 × KDP). PMTP has a three-dimensional crystal structure of corner-shared MgO4, PO4, and TeO6 polyhedra, which form a [TeMg3P2O14]∞ framework. Electronic structure calculations revealed that the stereoactive lone pair on the Pb(2+) cation is critical to producing the substantial NLO response and that the NLO activity is further enhanced by the presence of triply bidentate Te(6+) cations found in Te-O-O-Pb rings." @default.
- W2238024636 created "2016-06-24" @default.
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- W2238024636 date "2015-12-24" @default.
- W2238024636 modified "2023-10-10" @default.
- W2238024636 title "Bidenticity-Enhanced Second Harmonic Generation from Pb Chelation in Pb<sub>3</sub>Mg<sub>3</sub>TeP<sub>2</sub>O<sub>14</sub>" @default.
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- W2238024636 doi "https://doi.org/10.1021/jacs.5b11712" @default.
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