Matches in SemOpenAlex for { <https://semopenalex.org/work/W2238560052> ?p ?o ?g. }
- W2238560052 endingPage "403" @default.
- W2238560052 startingPage "389" @default.
- W2238560052 abstract "AbstractThe rate of substitution of the chloride ligand in 1,3-bis(pyridyl)benzene platinum(II) chloride (Pt1), 1,3-bis(N-pyrazolyl)benzene platinum(II) chloride (Pt2), 1,3-bis(8-quinolyl)benzene platinum(II) chloride (Pt3), and 1,3-bis(7-azaindolyl)benzene platinum(II) chloride (Pt4) by three neutral nucleophiles with different steric demands, thiourea (Tu), N,N’-dimethylthiourea (Dmtu), and N,N,N,’N-tetramethylthiourea (Tmtu), was studied under pseudo-first-order conditions in methanol. The investigation was performed as a function of concentration and temperature using stopped-flow and UV–visible spectrophotometric techniques. The observed pseudo-first-order rate constants for substitution obeyed the rate law: . The reactivity of the rigid planar five-membered chelate complexes (Pt1 and Pt2) is influenced by the push and pull effect of the σ/π-character of the cis moieties, while in the six-membered complexes (Pt3 and Pt4) it is dependent on their structural topology and electronic features. The study ..." @default.
- W2238560052 created "2016-06-24" @default.
- W2238560052 creator A5056338738 @default.
- W2238560052 creator A5077417512 @default.
- W2238560052 date "2016-01-05" @default.
- W2238560052 modified "2023-09-23" @default.
- W2238560052 title "The deleterious effect of pyrollic-nitrogen on the substitution reactivity of tridentate N^C^N platinum(II) complexes. A kinetic and mechanistic study" @default.
- W2238560052 cites W12343461 @default.
- W2238560052 cites W1242125470 @default.
- W2238560052 cites W1595263782 @default.
- W2238560052 cites W1733225785 @default.
- W2238560052 cites W1899531169 @default.
- W2238560052 cites W1965612889 @default.
- W2238560052 cites W1966776365 @default.
- W2238560052 cites W1967111983 @default.
- W2238560052 cites W1967298519 @default.
- W2238560052 cites W1969332057 @default.
- W2238560052 cites W1973924961 @default.
- W2238560052 cites W1973962135 @default.
- W2238560052 cites W1976999900 @default.
- W2238560052 cites W1981375882 @default.
- W2238560052 cites W1986406178 @default.
- W2238560052 cites W1989180035 @default.
- W2238560052 cites W1993318870 @default.
- W2238560052 cites W1994544537 @default.
- W2238560052 cites W1994914121 @default.
- W2238560052 cites W1995810957 @default.
- W2238560052 cites W1995837528 @default.
- W2238560052 cites W1997338710 @default.
- W2238560052 cites W2001063959 @default.
- W2238560052 cites W2006113601 @default.
- W2238560052 cites W2006680993 @default.
- W2238560052 cites W2013783305 @default.
- W2238560052 cites W2014145884 @default.
- W2238560052 cites W2015202052 @default.
- W2238560052 cites W2017832858 @default.
- W2238560052 cites W2020247015 @default.
- W2238560052 cites W2020736879 @default.
- W2238560052 cites W2023271753 @default.
- W2238560052 cites W2026950328 @default.
- W2238560052 cites W2028027391 @default.
- W2238560052 cites W2035224391 @default.
- W2238560052 cites W2036640302 @default.
- W2238560052 cites W2040575909 @default.
- W2238560052 cites W2041655565 @default.
- W2238560052 cites W2042595063 @default.
- W2238560052 cites W2043610941 @default.
- W2238560052 cites W2045037933 @default.
- W2238560052 cites W2050840546 @default.
- W2238560052 cites W2063407177 @default.
- W2238560052 cites W2067760618 @default.
- W2238560052 cites W2071799453 @default.
- W2238560052 cites W2074923286 @default.
- W2238560052 cites W2076074961 @default.
- W2238560052 cites W2076491036 @default.
- W2238560052 cites W2081538434 @default.
- W2238560052 cites W2095238521 @default.
- W2238560052 cites W2112550753 @default.
- W2238560052 cites W2118566026 @default.
- W2238560052 cites W2119834806 @default.
- W2238560052 cites W2125505884 @default.
- W2238560052 cites W2133650309 @default.
- W2238560052 cites W2138996718 @default.
- W2238560052 cites W2143981217 @default.
- W2238560052 cites W2149711357 @default.
- W2238560052 cites W2150103922 @default.
- W2238560052 cites W2157436895 @default.
- W2238560052 cites W2165521501 @default.
- W2238560052 cites W2314455260 @default.
- W2238560052 cites W2321556913 @default.
- W2238560052 cites W2331690001 @default.
- W2238560052 cites W2335633107 @default.
- W2238560052 cites W2410395112 @default.
- W2238560052 cites W2429410638 @default.
- W2238560052 cites W2951040683 @default.
- W2238560052 cites W3022722767 @default.
- W2238560052 cites W67523284 @default.
- W2238560052 cites W2026731428 @default.
- W2238560052 cites W2605521122 @default.
- W2238560052 doi "https://doi.org/10.6084/m9.figshare.1614921" @default.
- W2238560052 hasPublicationYear "2016" @default.
- W2238560052 type Work @default.
- W2238560052 sameAs 2238560052 @default.
- W2238560052 citedByCount "0" @default.
- W2238560052 crossrefType "journal-article" @default.
- W2238560052 hasAuthorship W2238560052A5056338738 @default.
- W2238560052 hasAuthorship W2238560052A5077417512 @default.
- W2238560052 hasConcept C111185830 @default.
- W2238560052 hasConcept C116569031 @default.
- W2238560052 hasConcept C121332964 @default.
- W2238560052 hasConcept C142724271 @default.
- W2238560052 hasConcept C148898269 @default.
- W2238560052 hasConcept C155647269 @default.
- W2238560052 hasConcept C161790260 @default.
- W2238560052 hasConcept C170493617 @default.
- W2238560052 hasConcept C178790620 @default.
- W2238560052 hasConcept C178907741 @default.
- W2238560052 hasConcept C179104552 @default.