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- W2238745798 abstract "Abstract Some recent advances in the synthesis of optically active carotenoids with ɛ-end groups are presented. Methods for the preparation of appropriate optically active building units are discussed. Some previously unpublished work is described. This includes first syntheses of the following compounds: 1. Lutein group: (3R,3′R,6′R)-, (3S,3′S,6′S)-, (3R,3′S,6′S)- and (3S,3′R,6′R)-lutein, (3R,6′S)-3′- O-didehydrolutein (zeaxanthin metabolite). 2. Fritschiellaxanthin monoacetate. 3. Tunaxanthin group: Lactuca-xanthin, (3S,6S,3′S,6′S)-tunaxanthin, chiriquixanthin A, chiriquixanthin B, (3S, 6S,3′R,6′S)- and (3R,6S,3′R,6′S)-tunaxanthin (ent.-chiriquixanthin A and B), (3R, 6R,3′S,6′S)-(meso)- and (3S,6R,3′R,6′S)-(meso)-tunaxanthin, (3R,6R,3′R,6′S)/(3S,6S, 3′S,6′R) (rac.)-tunaxanthin, and (6S,6′S)-3,3′-O-tetradehydro-tunaxanthin (zeaxanthin metabolite). Chiroptical properties, NMR and HPLC analyses of some selected compounds are discussed." @default.
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- W2238745798 date "1982-01-01" @default.
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- W2238745798 title "SYNTHESIS OF OPTICALLY ACTIVE CAROTENOIDS WITH ɛ-END GROUPS" @default.
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- W2238745798 doi "https://doi.org/10.1016/b978-0-08-026224-6.50008-5" @default.
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