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- W2238783602 abstract "X-ray photoelectron spectroscopy (XPS) has been used to characterise the short range structure of iron phosphate glasses. Quantitative Fe 2+ /Fe 3+ ratios determined by decomposing the Fe3p spectra are in good agreement with valence measurements made by Mossbauer spectroscopy. Fe 2+ is preferred when [Fe]/[P] is low, whereas Fe 3+ is preferred when [Fe]/[P] is greater than ∼ 0.4. Increasing [Fe]/[P] decreases the bridging to nonbridging oxygen ratio determined from the OS1 spectra" @default.
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- W2238783602 date "1994-01-01" @default.
- W2238783602 modified "2023-09-27" @default.
- W2238783602 title "XPS Study of Iron Phosphate Glasses" @default.
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