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- W2239385006 abstract "This chapter deals with the exchange reactions of Group I, II, and III organometallic compounds. The actual degree of association depends on the alkyl group involved and the solvent. The nature of the association in these derivatives permits two types of exchange: group exchange between aggregates (intermolecular) and migration of groups within an aggregate. To account for the exchange, two alternate intramolecular paths were proposed in which rearrangement of the bridge bonds provides a mechanism for the transfer of the methyl groups. They also found that in the exchange of methyl groups between trimethylgallium or trimethylindium and trimethylaluminum the activation energy was within experimental error of that observed for the bridge-terminal exchange. The rates of exchange were the same in toluene solution but the methyl group exchange was a factor of ten slower than bridge-terminal exchange in cyclopentane solution. The main reason proposed for this is that the x-system of the unsaturated group interacts with the vacant nonbonding molecular orbitals of the aluminum atoms and this interaction stabilizes the bridge system." @default.
- W2239385006 created "2016-06-24" @default.
- W2239385006 creator A5043654905 @default.
- W2239385006 date "1970-01-01" @default.
- W2239385006 modified "2023-10-17" @default.
- W2239385006 title "Fast Exchange Reactions of Group I, II, and III Organometallic Compounds" @default.
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