Matches in SemOpenAlex for { <https://semopenalex.org/work/W2240909504> ?p ?o ?g. }
- W2240909504 endingPage "168" @default.
- W2240909504 startingPage "160" @default.
- W2240909504 abstract "Heteroleptic (C∧N)2Ir(acac) (C∧N = 4-CBppy (1); 5-CBppy (2), 4-fppy (4) CB = ortho-methylcarborane; ppy = 2-phenylpyridinato-C2,N, 4-fppy = 2-(4-fluorophenyl)pyridinato-C2,N, acac = acetylacetonate) complexes were prepared and characterized. While 1 exhibits a phosphorescence band centered at 531 nm, which is red-shifted compared to that of unsubstituted (ppy)2Ir(acac) (3) (λem = 516 nm), the emission spectrum of 2 shows a blue-shifted band at 503 nm. Comparison with the emission band for the 4-fluoro-substituted 4 (λem = 493 nm) indicates a substantial bathochromic shift in 1. Electrochemical and theoretical studies suggest that while carborane substitution on the 4-position of the phenyl ring lowers the 3MLCT energy by a large contribution to lowest unoccupied molecular orbital (LUMO) delocalization, which in turn assigns the lowest triplet state of 1 as [dπ(Ir)→π*(C∧N)] 3MLCT in character, the substitution on the 5-position raises the 3MLCT energy by the effective stabilization of the highest occupied molecular orbital (HOMO) level because of the strong inductive effect of carborane. An electroluminescent device incorporating 1 as an emitter displayed overall good performance in terms of external quantum efficiency (6.6%) and power efficiency (10.7 lm/W) with green phosphorescence." @default.
- W2240909504 created "2016-06-24" @default.
- W2240909504 creator A5044553288 @default.
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- W2240909504 creator A5071485475 @default.
- W2240909504 creator A5083938194 @default.
- W2240909504 creator A5090584934 @default.
- W2240909504 date "2012-12-20" @default.
- W2240909504 modified "2023-10-12" @default.
- W2240909504 title "Phosphorescence Color Tuning of Cyclometalated Iridium Complexes by <i>o</i>-Carborane Substitution" @default.
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