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- W2242470771 abstract "Abstract The subject matter of classical thermodynamics is the asymptotic behavior of equilibrium systems in thermodynamic limit, for small molecular systems, when transition to thermodynamic limit is impossible, the extension of thermodynamics is required. This work studies novel approach for the evaluation of partition functions of small systems by complex pole analysis. Several cases for molecular systems in small cavities are studied numerically. In particular size-dependent additional pressure for small systems is evaluated analytically and numerically. Similar approach was developed earlier in nuclear physics for finite systems of nucleons. The obtained results correspond to published experimental data and molecular dynamics simulations." @default.
- W2242470771 created "2016-06-24" @default.
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- W2242470771 date "2015-03-04" @default.
- W2242470771 modified "2023-09-23" @default.
- W2242470771 title "Complex Pole Approach in Thermodynamic Description of Fluid Mixtures with Small Number of Molecules" @default.
- W2242470771 hasPublicationYear "2015" @default.
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