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- W2243366302 abstract "Capacity fade with cycling of thin-film rechargeable Li/Lipon/V{sub 2}O{sub 5} cells, formed as electrochromic mirrors with ITO current collectors, has been studied by optical and impedance spectroscopy and extended cycling experiments. An irreversible decrease in the reflectivity observed in cells cycled between 3.6 to 1.5 V was attributed to a roughening of the Li surface at the Li-Lipon interface. Although the consequent loss of contact area might be the source of increasing cell resistance responsible for the capacity fade, this possibility was ruled out because of the large variability observed in the cycling performance of cells with different cathodes and the constancy of the reflectivity when the cutoff voltage was increased to 2.5 V. It was concluded from the analysis of impedance data that a decrease in Li{sup +} ion diffusivity in the cathode and the cathode-electrolyte interface with cycling is the major cause of capacity fade." @default.
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- W2243366302 date "1996-01-01" @default.
- W2243366302 modified "2023-09-27" @default.
- W2243366302 title "Capacity fade in thin-film lithium-V{sub 2}O{sub 5} cells" @default.
- W2243366302 hasPublicationYear "1996" @default.
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