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- W2243373302 abstract "In this work, hexagonal solid solutions of (Gd 0.95 Eu 0.05 )(OH) 3 with two distinctive morphologies of nanorods and nanotubes were successfully synthesized via hydrothermal treatment of mixed nitrate solutions in the presence of ammonium hydroxide. The hydroxide samples exhibited characteristic Eu 3+ photoluminescence through the energy transfer from Gd 3+ to Eu 3+ and the self-excitation of Eu 3+ . The hydroxide precursors transformed into cubic (Gd 0.95 Eu 0.05 ) 2 O 3 at ~500 °C via an intermediate monoclinic (Gd 0.95 Eu 0.05 )OOH phase, and the Eu 3+ coordination accordingly experienced symmetry changes from D 3h to C 2v , and then to C 2 /S 6 . The cubic (Gd 0.95 Eu 0.05 ) 2 O 3 well retained the original morphologies of their polycrystalline precursors and exhibited a single-crystalline character at 1000 °C. Greatly enhanced photoluminescence (~5000 times that of the hydroxides) was observed for the phase conversion." @default.
- W2243373302 created "2016-06-24" @default.
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- W2243373302 date "2011-08-01" @default.
- W2243373302 modified "2023-09-25" @default.
- W2243373302 title "(Gd<sub>0.95</sub>Eu<sub>0.05</sub>)(OH)<sub>3</sub> Nanomaterials via Hydrothermal Processing and their Transformation into Single Crystalline (Gd<sub>0.95</sub>Eu<sub>0.05</sub>)<sub>2</sub>O<sub>3</sub> with Enhanced Photoluminescence" @default.
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- W2243373302 doi "https://doi.org/10.4028/www.scientific.net/amr.320.309" @default.
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