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- W2244298773 abstract "Specific, intrinsic rates and product distributions for CO/sub 2/ hydrogenation on Ni/SiO/sub 2/ were determined at 500 to 575 K, 140 to 2500 kPa, and a range of space velocities. The data show that the turnover number for O/sub 2/ methanation on nickel is the same as for CO methanation at 525 K; apparent activation energies ofr CH/sub 4/ formation are 96 and 80 kJ/mol in CO and CO/sub 2/ hydrogenation, respectively. Besides methane, CO and small amounts of C/sub 2/ hydrocarbons are produced as products of CO/sub 2/ methanation; the product distribution is a function of space velocity from 4000 to 49,000 h/sup -1/, the yield of methane being significantly higher at low space velocities. Results of conversion vs temperature tests show that the production of CH/sub 4/ is higher from CO than CO/sub 2/ hydrogenation over the temperature range 500 to 727 K." @default.
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- W2244298773 date "1981-03-01" @default.
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- W2244298773 title "Hydrogenation of CO/sub 2/ on group VIII metals. I. Specific activity of Ni/SiO/sub 2/" @default.
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