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• W2244369951 abstract "The ternary germanide Ce3Ni2Ge7 has been studied by means of neutron powder diffraction and Ce LIII X-ray absorption (XAS). This compound which orders antiferromagnetically below TN=7.2(2) K, crystallizes in the orthorhombic (Cmmm space group) La3Co2Sn7-type structure where Ce atoms occupying two inequivalent crystallographic sites: Ce1 at 2d site and Ce2 at 4i site. Below TN, the antiferromagnetic structure of Ce3Ni2Ge7 is collinear but only the Ce2 atoms carry a magnetic moment (1.98(2) μB at 1.4 K). The absence of ordered magnetic moment on Ce1 atoms can be correlated to the average valence v=3.03(1), determined by X-ray absorption spectroscopy, suggesting an intermediate valence state of cerium in the 2d site." @default.
• W2244369951 created "2016-06-24" @default.
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• W2244369951 date "2001-07-01" @default.
• W2244369951 modified "2023-10-18" @default.
• W2244369951 title "Magnetic structure of the ternary germanide Ce3Ni2Ge7" @default.
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• W2244369951 doi "https://doi.org/10.1016/s0304-8853(01)00189-5" @default.
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