Matches in SemOpenAlex for { <https://semopenalex.org/work/W2244753148> ?p ?o ?g. }
- W2244753148 endingPage "2246" @default.
- W2244753148 startingPage "2243" @default.
- W2244753148 abstract "The reaction mechanism of the decomposition of ethoxy species to ethene and acidic OH groups on H-ZSM-5 was studied by IR spectroscopy using isotope-labeled ethanol. The concerted mechanism occurring on both the ethoxy (acid) site and the counterpart lattice oxygen was suggested by GC-MS analysis of evolved d2-ethene and IR observation of the recovery of OH s groups on acid sites from the decomposition of CH3CD2O– ethoxy species. The concerted mechanism was further confirmed by the estimation of activation energy for decomposition of CH3CH2O–, CH3CD2O–, and CD3CD2O– ethoxy species, 122 ± 3, 125 ± 3, and 140 ± 5 kJ mol–1, respectively, where the kinetic isotope effect was observed for the cleavage of the CH or CD bond of the methyl group of the ethoxy species." @default.
- W2244753148 created "2016-06-24" @default.
- W2244753148 creator A5001511833 @default.
- W2244753148 creator A5039390377 @default.
- W2244753148 creator A5055019536 @default.
- W2244753148 creator A5074713586 @default.
- W2244753148 creator A5089311687 @default.
- W2244753148 date "2015-06-03" @default.
- W2244753148 modified "2023-10-16" @default.
- W2244753148 title "Mechanism of Decomposition of Surface Ethoxy Species to Ethene and Acidic OH Groups on H-ZSM-5" @default.
- W2244753148 cites W161186051 @default.
- W2244753148 cites W1963782086 @default.
- W2244753148 cites W1964194813 @default.
- W2244753148 cites W1971307712 @default.
- W2244753148 cites W1976431617 @default.
- W2244753148 cites W1991014595 @default.
- W2244753148 cites W1994688650 @default.
- W2244753148 cites W2007265670 @default.
- W2244753148 cites W2011424093 @default.
- W2244753148 cites W2012021969 @default.
- W2244753148 cites W2023053035 @default.
- W2244753148 cites W2031293654 @default.
- W2244753148 cites W2038648700 @default.
- W2244753148 cites W2041146051 @default.
- W2244753148 cites W2046252470 @default.
- W2244753148 cites W2047613306 @default.
- W2244753148 cites W2058911496 @default.
- W2244753148 cites W2060183674 @default.
- W2244753148 cites W2065764782 @default.
- W2244753148 cites W2066373136 @default.
- W2244753148 cites W2066524922 @default.
- W2244753148 cites W2071014716 @default.
- W2244753148 cites W2072509266 @default.
- W2244753148 cites W2074789420 @default.
- W2244753148 cites W2077992505 @default.
- W2244753148 cites W2087385869 @default.
- W2244753148 cites W2087554092 @default.
- W2244753148 cites W2094245044 @default.
- W2244753148 cites W2102451648 @default.
- W2244753148 cites W2141565159 @default.
- W2244753148 cites W2145745436 @default.
- W2244753148 cites W2146301006 @default.
- W2244753148 cites W2315767686 @default.
- W2244753148 cites W2322016220 @default.
- W2244753148 cites W2328684762 @default.
- W2244753148 cites W2334733100 @default.
- W2244753148 cites W896345 @default.
- W2244753148 doi "https://doi.org/10.1021/acs.jpclett.5b00846" @default.
- W2244753148 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/26266598" @default.
- W2244753148 hasPublicationYear "2015" @default.
- W2244753148 type Work @default.
- W2244753148 sameAs 2244753148 @default.
- W2244753148 citedByCount "23" @default.
- W2244753148 countsByYear W22447531482015 @default.
- W2244753148 countsByYear W22447531482016 @default.
- W2244753148 countsByYear W22447531482017 @default.
- W2244753148 countsByYear W22447531482018 @default.
- W2244753148 countsByYear W22447531482019 @default.
- W2244753148 countsByYear W22447531482020 @default.
- W2244753148 countsByYear W22447531482021 @default.
- W2244753148 countsByYear W22447531482022 @default.
- W2244753148 crossrefType "journal-article" @default.
- W2244753148 hasAuthorship W2244753148A5001511833 @default.
- W2244753148 hasAuthorship W2244753148A5039390377 @default.
- W2244753148 hasAuthorship W2244753148A5055019536 @default.
- W2244753148 hasAuthorship W2244753148A5074713586 @default.
- W2244753148 hasAuthorship W2244753148A5089311687 @default.
- W2244753148 hasConcept C105281773 @default.
- W2244753148 hasConcept C124681953 @default.
- W2244753148 hasConcept C153642686 @default.
- W2244753148 hasConcept C155647269 @default.
- W2244753148 hasConcept C161790260 @default.
- W2244753148 hasConcept C178790620 @default.
- W2244753148 hasConcept C185592680 @default.
- W2244753148 hasConcept C2778533180 @default.
- W2244753148 hasConcept C2780263894 @default.
- W2244753148 hasConcept C29135686 @default.
- W2244753148 hasConcept C65024703 @default.
- W2244753148 hasConcept C71240020 @default.
- W2244753148 hasConcept C75473681 @default.
- W2244753148 hasConcept C90150868 @default.
- W2244753148 hasConceptScore W2244753148C105281773 @default.
- W2244753148 hasConceptScore W2244753148C124681953 @default.
- W2244753148 hasConceptScore W2244753148C153642686 @default.
- W2244753148 hasConceptScore W2244753148C155647269 @default.
- W2244753148 hasConceptScore W2244753148C161790260 @default.
- W2244753148 hasConceptScore W2244753148C178790620 @default.
- W2244753148 hasConceptScore W2244753148C185592680 @default.
- W2244753148 hasConceptScore W2244753148C2778533180 @default.
- W2244753148 hasConceptScore W2244753148C2780263894 @default.
- W2244753148 hasConceptScore W2244753148C29135686 @default.
- W2244753148 hasConceptScore W2244753148C65024703 @default.
- W2244753148 hasConceptScore W2244753148C71240020 @default.
- W2244753148 hasConceptScore W2244753148C75473681 @default.
- W2244753148 hasConceptScore W2244753148C90150868 @default.
- W2244753148 hasIssue "12" @default.
- W2244753148 hasLocation W22447531481 @default.
- W2244753148 hasLocation W22447531482 @default.