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- W2245488515 abstract "The hydrogenation of benzene was investigated over amorphous Ni-Zr alloys with different Ni compositions (Ni{33}Zr{67}, Ni{40}Zr{60, Ni{50}Zr{50}, Ni{70}Zr{30}, Ni{90}Zr{10}) produced by a rapid solidification technique. Although the catalytic activities of the alloys were very low in the virgin state, they gradually increased with increasing number of regeneration (oxidation and reduction) reaction cycles, and the activity approached constant value after six regenerations. The benzene hydrogenation activity increased with Ni content up to 50%, but it decreased with the nickel content. It was shown that the surface area measured by nitrogen adsorption method had almost the same dependence on Ni content. These results suggest that Ni{50}Zr{50} alloy is easily relaxed by the regeneration, and Ni atoms effective for the hydrogenation are highly dispersed on the micro ZrO{2} crystals produced from the alloy by the oxidation." @default.
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- W2245488515 date "1993-01-01" @default.
- W2245488515 modified "2023-09-22" @default.
- W2245488515 title "Benzene Hydrogenation Activity of Amorphous Ni-Zr Alloy" @default.
- W2245488515 hasPublicationYear "1993" @default.
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