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- W2246064805 abstract "The quadrupole interaction energy $mathrm{eqQ}$ for ${mathrm{Li}}^{7}$ in ${mathrm{Li}}_{2}$ has been reported to be positive. In an attempt to determine $Q({mathrm{Li}}^{7})$ a calculation of $q$ has been made using two approximate wave functions for ${mathrm{Li}}_{2}$. One of these is a Heitler-London function including inner shells and the other a twelve term variational function. The two functions lead to dissociation energies of 0.27 ev and 0.48 ev, respectively. The experimental value is 1.14 ev.The results of the two calculations differ in sign. The more accurate variational function leads to a negative $q$ and consequently a negative value of $Q({mathrm{Li}}^{7})$. Unfortunately, the electronic and nuclear parts of $q$ are nearly equal in ${mathrm{Li}}_{2}$ so that the magnitude and even the sign are still uncertain." @default.
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- W2246064805 date "1953-05-15" @default.
- W2246064805 modified "2023-10-14" @default.
- W2246064805 title "The Quadrupole Moment ofLi7" @default.
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- W2246064805 doi "https://doi.org/10.1103/physrev.90.585" @default.
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