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• W2246618888 abstract "ε-Caprolactam was synthesized directly from cyclohexanol via a tandem catalytic process using [n-C16H33N(CH3)3]H2PW12O40 as a catalyst. The highly efficient performance of the catalysts is due to the phase-transfer function of cation, improved coordination with peroxotungsten during oxidation and stabilization function of heteropoly anion on the intermediate formed during Beckmann rearrangement. A ε-caprolactam yield of 73.9% was obtained with a cyclohexanol conversion of 97.1% under optimized conditions." @default.
• W2246618888 created "2016-06-24" @default.
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• W2246618888 date "2015-10-01" @default.
• W2246618888 modified "2023-09-24" @default.
• W2246618888 title "Direct catalytic synthesis of ε-caprolactam from cyclohexanol using [n-C16H33N (CH3)3]H2PW12O40 as a catalyst" @default.
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• W2246618888 doi "https://doi.org/10.1016/j.catcom.2015.07.006" @default.
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