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- W2247222039 abstract "The noteworthy structural feature of the title complex, poly[acetonitriletetra-μ2-thiocyanato-barium(II)digold(I)], {[Au2Ba(SCN)4(CH3CN)]}n, is that the bis(thiocyanato)aurate(I) anion adopts both monomeric and trimeric motifs. The trimer unit has an Au⋯Au distance of 3.1687 (3) Å. In both the monomeric and trimeric units, the AuI atoms are also bonded to two S atoms. Within the trimeric unit, the AuI atoms exist in differing environments; one Au atom has a T-shaped three-coordinate geometry while the other has a square-planar four-coordinate geometry. The AuI atom of the monomer adopts a linear two-coordinate geometry. The extended structure can be described as a three-dimensional coordination polymer consisting of chains of Ba atoms bridged by thiocyanate N atoms. These chains are cross-linked via the gold monomeric and trimeric units." @default.
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- W2247222039 date "2010-06-09" @default.
- W2247222039 modified "2023-09-26" @default.
- W2247222039 title "{Ba[Au(SCN)<sub>2</sub>]<sub>2</sub>}<sub><i>n</i></sub>: a three-dimensional net comprised of monomeric and trimeric gold(I) units" @default.
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- W2247222039 doi "https://doi.org/10.1107/s1600536810021276" @default.
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