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- W2247283496 abstract "Systematic studies were made to establish the reactivities of thiphene, benzo(b)thiphene, dibenzothiophene, and benzo(b)naphthol(2, 3-d)thiophene at a high pressure (71 atm) representative of industrial practice. The experiments were done with an autoclave reactor containing suspended particles of a standard commercial hydrodesulfurization catalyst, sulfided CoO-MoO/sub 3//..gamma..-Al/sub 2/O/sub 3/. The rate constants are tabulated and show that the reactivity sharply decreases as the number of rings in the reactant decreases from 1 to 3, but the four-ring compound is slightly more reactive than the three-ring compound. These results indicate that dibenzothiophene as the reactant most in need of study as it may be considered a representative compound for heavy petroleum feedstocks and coal-derived liquids. (JSR)" @default.
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- W2247283496 date "1979-05-01" @default.
- W2247283496 modified "2023-09-27" @default.
- W2247283496 title "Hydrodesulfurization of polycyclic aromatics catalyzed by sulfided CoO--MoO/sub 3//. gamma. -Al/sub 2/O/sub 3/: the relative reactivities" @default.
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