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• W2247301426 abstract "Four alloys with nominal compositions Ni 46 Mn 41.5-x Fe x Sn 12.5 (x=0, 2, 4, 6 at.%) were cast in an induction vacuum furnace and homogenized. Then they were melted in quartz tubes and ejected onto a rotating copper wheel to produce ribbons. The X-Ray phase analyses of as melt spun ribbons have shown that in both, the ternary as well as in the quaternary alloys a single phase of the Heusler L2 1 type ordered structure was found. The characteristic temperatures of magnetic (T C ) and martensitic (M s ) transformations were determined by a vibrating sample magnetometer (VSM). Both the M s and T C increase with the increase of Fe content in all alloys, which is in accordance with the theory of valence electron concentration (e/a) influence on M s . The phase structures, chemical compositions, grains sizes and type of microsegregation were characterized by transmission electron microscope (TEM). The equi-axed grains of size from 0.95 to 1.7 μm were observed in all ribbons. The grains posses the L2 1 structure at room temperature, however in the alloys with higher Fe content the different type of martensite was observed at the grain boundaries of L2 1 phase. Appearance of this martensite was explained in relation to microsegregation of particular elements during melt spinning process and simultaneous change in the e/a ratio." @default.
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• W2247301426 date "2014-04-01" @default.
• W2247301426 modified "2023-09-23" @default.
• W2247301426 title "Magnetic and Martensitic Transformations in Ni₄₆Mn_41.5-xFe_xSn_12.5 Melt Spun Ribbons" @default.
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• W2247301426 doi "https://doi.org/10.4028/www.scientific.net/msf.782.23" @default.
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