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- W2247602402 abstract "A quenching-triggered reversible single-crystal-to-single-crystal (SC-SC) phase transition was discovered in a metal-organic framework (MOF) PCN-526. During the phase transition, the one-dimensional channel of PCN-526 distorts from square to rectangular in shape while maintaining single crystallinity. Although SC-SC transformations have been frequently observed in MOFs, most reports have focused on describing the resulting structural alterations without shedding light on the mechanism for the transformation. Interestingly, modifying the occupancy or species of metal ions in the extra-framework sites, which provides mechanistic insight into the causes for the transformation, can forbid this phase transition. Moreover, as a host scaffold, PCN-526 presents a platform for modulation of the photoluminescence properties by encapsulation of luminescent guest molecules. Through judicious choice of these guest molecules, responsive luminescence caused by SC-SC transformations can be detected, introducing a new strategy for the design of novel luminescent MOF materials." @default.
- W2247602402 created "2016-06-24" @default.
- W2247602402 creator A5009527477 @default.
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- W2247602402 date "2015-06-09" @default.
- W2247602402 modified "2023-10-16" @default.
- W2247602402 title "A Reversible Crystallinity-Preserving Phase Transition in Metal–Organic Frameworks: Discovery, Mechanistic Studies, and Potential Applications" @default.
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- W2247602402 doi "https://doi.org/10.1021/jacs.5b02999" @default.
- W2247602402 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/26011818" @default.
- W2247602402 hasPublicationYear "2015" @default.
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