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- W2247863344 endingPage "7466" @default.
- W2247863344 startingPage "7461" @default.
- W2247863344 abstract "A water-soluble π-conjugated bispyridinium phenylenevinylene-based fluorogenic probe has been developed as a novel fluorescent chemosensor for highly selective, sensitive, and rapid detection of NO3(-) anion in acidic aqueous media. This system self-assembles to a nanoribbon as a result of ionic interaction. The positively charged chemosensor generates a nearly instantaneous significant fluorescence signal (475 vs 605 nm) in response to NO3(-) in the green/yellow spectral region, with a large Stokes shift (130 nm). The fluorescence changes can be attributed to the self-aggregation of the sensor triggered by ionic interaction, which occurs as a consequence of the subtle cooperation of electrostatic ionic bonding, van der Waals forces, and π-stacking of the π-conjugated aromatic moieties. Importantly, this chemosensor has been employed for the first time for the fluorescence detection of intracellular NO3(-) anion in cultured cells." @default.
- W2247863344 created "2016-06-24" @default.
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- W2247863344 date "2015-06-29" @default.
- W2247863344 modified "2023-10-03" @default.
- W2247863344 title "Anion Recognition Triggered Nanoribbon-Like Self-Assembly: A Fluorescent Chemosensor for Nitrate in Acidic Aqueous Solution and Living Cells" @default.
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- W2247863344 doi "https://doi.org/10.1021/acs.analchem.5b01774" @default.
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- W2247863344 hasPublicationYear "2015" @default.
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