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- W2247913384 abstract "The behaviour of catalytic chain transfer in semi-batch emulsion polymerisation has been studied for methyl methacrylate. Two different catalytic chain transfer reagents were used with different water solubilities: cobaloxime boron fluoride (COBF) which was found to partition approximately equally between organic and aqueous phases, and tetra-phenyl cobaloxime boron fluoride (COPhBF) which was found to reside predominantly in the organic phase. The difference in hydrophilicity between the two transfer agents was found to affect the polymerisation mechanism. COBF exhibited superior transfer behaviour in all cases whereas the restricted mobility of the COPhBF had a deleterious effect on the efficiency of the transfer mechanism. The best results were achieved under monomer flooded conditions, using COBF. MALDI analysis shows catalytic chain transfer to be the mechanism dominating initiation and termination of chains as none of the chains appear to have initiator fragment end-groups." @default.
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- W2247913384 date "1996-01-01" @default.
- W2247913384 modified "2023-09-27" @default.
- W2247913384 title "Use of Cobalt Catalysts to Control the Production of Low Molecular Weight Polymers" @default.
- W2247913384 hasPublicationYear "1996" @default.
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