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- W2248960818 abstract "Nano-crystalline Co 0.6 Zn 0.4 Cu 0.2 Cr x Fe 1.8-x O 4 (x = 0.2, 0.4, 0.6 and 0.8), have been synthesized using a citrate sol-gel auto combustion method and annealed at different temperature 400 ° C, 600 ° C, 800 ° C and 1000 ° C. The effect of chromium substitution on the structural, magnetic and dielectric properties of cobalt-zinc-copper ferrite has been studied. The structural and magnetic characteristics have been studied by X-ray diffraction (XRD), Fourier Transform Infrared (FTIR) and Vibrating Sample Magnetometer (VSM) techniques. The X-ray diffractogram of all the annealed samples confirm the formation of single phase with Fd-3m space group. The crystalline sizes have been found to increase (from ~15 nm – to 60 nm) with the annealing temperature. The DC electrical resistivity of all the ferrites has been measured using a two-probe method between temperature range of 30 ° C to 100 ° C. The DC electrical resistivity of all the samples decrease with increase in temperature indicates semiconducting nature. However, the DC resistivity increase as the Cr 3+ concentration increases because the Cr 3+ ions enter the octahedral sites and reduce the electron exchange between Fe 2+ and Fe 3+ causing a decrease in polaron hopping of Fe 2+ -Fe 3+ ions. The value of the Seebeck coefficient (S) for all the ferrites is found to be positive indicating that all the ferrite samples behave as p-type semiconductors. The effect of copper chromium cation distribution among the tetrahedral (A) and octahedral (B) sites of Co-Zn substituted ferrite on magnetization and coercivity field have been investigated using VSM (vibrating sample magnetometer) technique. The decrease in the saturation magnetization (M s ) with increasing chromium content may be attributed to the copper and chromium enters into the octahedral site of the Co-Zn ferrite." @default.
- W2248960818 created "2016-06-24" @default.
- W2248960818 creator A5027435946 @default.
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- W2248960818 date "2013-05-01" @default.
- W2248960818 modified "2023-09-27" @default.
- W2248960818 title "Effect of Chromium Substitution on the Structural, Magnetic and Electrical Properties of Nano Crystalline Co<sub>0.6</sub>Zn<sub>0.4</sub>Cu<sub>0.2</sub>Cr<sub>x</sub>Fe<sub>1.8-x</sub>O<sub>4</sub> Ferrite" @default.
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- W2248960818 doi "https://doi.org/10.4028/www.scientific.net/ssp.202.173" @default.
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