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- W224949499 abstract "Optical absorption and fluorescence data were studied for the 4f/sub 2/ configuration of Pr/sup 3 +/ in CaWO/sub 4/. The absorption spectrum was recorded over the wavelength region from 0.3 to 2.5 micrometers at crystal temperatures of 25 and 85 K. The crystals were grown from a melt containing 1.0 atomic percent Pr/sup 3 +/. These absorption data were correlated with reported fluorescence data to establish energy levels in all the terms, except the singlet S; corresponding theoretical levels were obtained by diagonalizing a Hamiltonian containing the free-ion and crystal-field interactions in a basis of states spanning the ground configuration. A least-rms deviation of 18.3/cm between measured and calculated energy levels was obtained by varying the parameters of this Hamiltonian. Calculated g factors were also obtained for the energy degenerate doublets. (GRA)" @default.
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- W224949499 date "1975-11-01" @default.
- W224949499 modified "2023-09-27" @default.
- W224949499 title "Optical spectra and analysis of Pr/sup 3 +/ in CaWO/sub 4/. Technical report. [25 and 85 K, 1. 0 at. % Pr/sup 3 +/]" @default.
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