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- W224975943 abstract "We determined the cation distribution and ordering of Si, Al and Fe on the tetrahedral sites of a monoclinic low-sanidine from Itrongay, Madagascar, by combined neutron- and X-ray single-crystal diffraction. The cation distribution was determined by means of a simultaneous refinement using neutron- and X-ray data, as well as by combining scattering densities obtained from separate refinements with chemical data from a microprobe experiment. The two methods give the same results and show that Fe is fully ordered on T1, whereas Al shows a high degree of disorder. Based on this and previously published temperature-dependent X-ray data, we conclude that it is preferential ordering of Fe on T1 even at high temperature, rather than a high diffusion kinetics of Fe, which causes this asymmetry in ordering behavior between Al and Fe. The preferential ordering of Fe3+ relative to Al3+ in T1 is consistent with its 25 percent larger ionic radius." @default.
- W224975943 created "2016-06-24" @default.
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- W224975943 date "2005-05-02" @default.
- W224975943 modified "2023-10-16" @default.
- W224975943 title "Cation distribution in a Fe-bearing K-feldspar from Itrongay,Madagascar. A combined neutron- and X-ray single crystal diffractionstudy" @default.
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