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- W2250878894 abstract "Sodium-containing having as general formula NaxVOPOP4.(2 - x)H20 (0.25 ~< x < 0.50) have been obtained and characterized. Orthorhombic phases, which essentially maintain the structure of the layered oxide hydrate VOPO4.2H20 result. Intercalated sodium ions act as 'pillars'. The presence of n30 § ions in the parent VOPO4-2H20 and also in some reduced phases, is detected. The understanding of the structural role of the water molecules is advanced and the topotactic dehydration/rehydration processes are studied. The formation of a new metastable VOPO4.H20 phase is established." @default.
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- W2250878894 date "1988-01-01" @default.
- W2250878894 modified "2023-10-11" @default.
- W2250878894 title "Vanadyl Phosphate Dihydrate, a Solid Acid: The Role of Water in VOPO42H20 and its Sodium Derivatives" @default.
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