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- W2252438735 abstract "This study details the formal hydrogenation of two magnesium(I) dimers {(Nacnac)Mg}2 (Nacnac = [{(C6H3R2-2,6)NCMe}2CH](-); R = Pr(i) ((Dip)Nacnac), Et ((Dep)Nacnac)) using 1,3-cyclohexadiene. These reactions afford the magnesium(II) hydride complexes, {(Nacnac)Mg(μ-H)}2. Their reactions with excess CO are sterically controlled and lead cleanly to different C-C coupled products, viz. the ethenediolate complex, ((Dip)Nacnac)Mg{κ(1)-O-[((Dip)Nacnac)Mg(κ(2)-O,O-O2C2H2)]}, and the first cyclopropanetriolate complex of any metal, cis-{((Dep)Nacnac)Mg}3{μ-C3(H3)O3}. Computational studies imply the CO activation processes proceed via very similar mechanisms to those previously reported for related reactions involving f-block metal hydride compounds. This work highlights the potential magnesium compounds hold for use in the Fischer-Tropsch-like transformation of CO/H2 mixtures to value added oxygenate products." @default.
- W2252438735 created "2016-06-24" @default.
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- W2252438735 date "2015-07-09" @default.
- W2252438735 modified "2023-10-01" @default.
- W2252438735 title "Activation of CO by Hydrogenated Magnesium(I) Dimers: Sterically Controlled Formation of Ethenediolate and Cyclopropanetriolate Complexes" @default.
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- W2252438735 doi "https://doi.org/10.1021/jacs.5b06439" @default.
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