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- W2254168122 abstract "Abstract Five unprecedented pyridyl–oxazole oligomers exhibiting either linear or branched connectivity of their subunits were developed as a family of potential G‐quadruplex‐interacting ligands. Our synthesis employed variations of a key Pd/Cu‐mediated C–C cross‐coupling/C–H activation reaction to gain access to the oligomer products from a small set of substituted pyridine building blocks. The effect of the compounds on the conformation of a c‐myc oncogene promoter G‐quadruplex was investigated by circular dichroism under various conditions. Some or all of the compounds induced detectable helicity enhancement in low‐cation and Na + ‐rich Tris‐HCl (pH 7.4) buffers, respectively, in which the helix was only partially prefolded." @default.
- W2254168122 created "2016-06-24" @default.
- W2254168122 creator A5029219347 @default.
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- W2254168122 date "2015-11-24" @default.
- W2254168122 modified "2023-10-16" @default.
- W2254168122 title "Linear and Branched Pyridyl-Oxazole Oligomers: Synthesis and Circular Dichroism Detectable Effect on c-Myc G-Quadruplex Helicity" @default.
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- W2254168122 doi "https://doi.org/10.1002/ejoc.201501269" @default.
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