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- W2255248844 abstract "The synthesis of fluorescent N6-methyl-2-(1,2,3-triazol-1-yl)-2′-deoxyriboadenosine (AOz) was achieved by methylamine induced nucleophilic aromatic substitution of the corresponding 2,6-bis-(1,2,3-triazol-1-yl)purine 2′-deoxyribonucleoside. The developed fluorophore exhibits quantum yields of 20% and 12% in methanol and water, respectively. It was further applied in the synthesis of trinucleotide GAOzC which sustains a reasonable Stokes shift of 121 nm and 7% quantum yield upon irradiation at 310 nm. It was also demonstrated that Cu(I) species reduce 2,6-diazido purine derivatives regioselectively at C(6) providing a practical entry to 6-amino-2-azido-purine nucleosides." @default.
- W2255248844 created "2016-06-24" @default.
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- W2255248844 date "2016-03-01" @default.
- W2255248844 modified "2023-10-13" @default.
- W2255248844 title "Development of N6-methyl-2-(1,2,3-triazol-1-yl)-2′-deoxyadenosine as a novel fluorophore and its application in nucleotide synthesis" @default.
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- W2255248844 doi "https://doi.org/10.1016/j.tetlet.2016.02.003" @default.
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