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• W2255573670 abstract "In the structure of the title complex salt, (Et 2 NH 2 ) 2 [CuCl 4 ], the asymmetric unit consists of four unique diethylammonium cations and three unique tetrachloridocuprate anions. Two of the three anions are located with their copper atoms on independent crystallographic twofold axes, while the remaining tetrachloridocuprate is located at a general position of the orthorhombic space group P 2 1 2 1 2. Two of the three Cu atoms adopt a distorted square-planar/disphenoidal geometry and the third Cu atom has a regular square-planar coordination environment. The diethylammonium cations form an extensive hydrogen-bonded network through N—H...Cl interactions with the tetrachloridocuprate anions, resulting in a two-dimensional sheet-like hydrogen-bonded network parallel to the ab direction. The complex was observed to undergo a color shift from deep green at room temperature to pale yellow at temperatures above 328 K." @default.
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• W2255573670 date "2016-01-01" @default.
• W2255573670 modified "2023-09-25" @default.
• W2255573670 title "Crystal structure of the thermochromic bis(diethylammonium) tetrachloridocuprate(II) complex" @default.
• W2255573670 cites W1969360633 @default.
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• W2255573670 doi "https://doi.org/10.1107/s2056989015023348" @default.
• W2255573670 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/4704760" @default.
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