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- W2256187839 abstract "The lattice theory of liquids consisting of rodlike molecules is presented and discussed with emphasis on polymers exhibiting nematic or cholesteric liquid crystallinity. Steric repulsions between the solute particles are principally responsible for order in lyotropic liquid-crystalline systems. In the case of rigid rods, the axial ratio of the particles governs the concentration at which separation of a nematic or cholesteric phase sets in. For semi-rigid chains such as those of cellulose and its derivatives, the axial ratio of the Kuhn segment is the relevant parameter. These and other predictions of the lattice theory are confirmed by numerous experiments. Liquid crystallinity may be promoted by orientation-dependent intermolecular attractions between extended chain molecules. Such forces originate in the anisotropy of the polarizabilities of groups, e.g., phenylene, in the main chain. They may be especially important in thermotropic melts and concentrated solutions." @default.
- W2256187839 created "2016-06-24" @default.
- W2256187839 creator A5058114693 @default.
- W2256187839 date "1984-01-01" @default.
- W2256187839 modified "2023-10-06" @default.
- W2256187839 title "Molecular theory of liquid crystals" @default.
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- W2256187839 doi "https://doi.org/10.1007/3-540-12818-2_5" @default.
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