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• W2256390892 abstract "BACKGROUND This work evaluates hollow fiber liquid–liquid membrane contactors (HFMC) as a polishing step for the removal of low levels of ammonium from water purified by (or being supplied to) a membrane distillation unit in order to fulfil the conductivity requirements of hydrogen production by water electrolysis. RESULTS The influence of the operating conditions (flow, pH, ammonium concentration, buffer capacity) were evaluated under a closed-loop setup in order to achieve a reduction of total ammonia concentration in water, from 15 to 1 mg L−1 to assure the production of water in the membrane distillation with a conductivity lower than 1 µS cm−1. These values were used to validate a numerical algorithm describing the system performance. In order to reach the ammonia concentration requirements and considering the low concentration of bicarbonate (low pH buffer capacity) in the treated water a buffer agent was added to the working solution. CONCLUSIONS HFMC technology is a suitable solution to remove low levels of ammonium from water to values as low as 1 mg L−1NH3 through appropriate control of pH. The ammonium removal efficiency of the HFMC was improved by raising the pH or the flow rate. Finally, the model proposed provides a good description of the membrane contactor performance with minimal deviations when compared with experimental results. © 2016 Society of Chemical Industry" @default.
• W2256390892 created "2016-06-24" @default.
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• W2256390892 date "2016-03-18" @default.
• W2256390892 modified "2023-10-13" @default.
• W2256390892 title "Trace ammonium removal by liquid-liquid membrane contactors as water polishing step of water electrolysis for hydrogen production from a wastewater treatment plant effluent" @default.
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• W2256390892 doi "https://doi.org/10.1002/jctb.4923" @default.
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