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• W2256570036 abstract "We report the first examples of straightforward trans-hydroboration of internal alkynes at room temperature with 9-BBN, producing five-membered BN-heterocycles. Contrary to conventional cis-hydroboration, we demonstrate that the introduction of a pyridyl group switches the stereoselectivity of the reaction. A hydride migration mechanism has been proposed and supported by DFT calculations for the trans-hydroboration. This new hydroboration approach allows facile construction of new blue fluorescent BN-heterocyclic compounds." @default.
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• W2256570036 date "2016-02-01" @default.
• W2256570036 modified "2023-10-14" @default.
• W2256570036 title "Pyridyl Directed Catalyst-Free <i>trans</i>-Hydroboration of Internal Alkynes" @default.
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• W2256570036 doi "https://doi.org/10.1021/acs.orglett.5b03698" @default.
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