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- W2256650065 abstract "Detailed column dynamics of multicomponent adsorption displacement chromatography were simulated with a general rate equation model. The effects of feed volume, displacer concentration, displacer affinity, and displacer amount on the displacement effluent histories were illustrated. The simulation results show that, in order for the displacement train to be developed, the displacer concentration must be higher than a critical value determined from the affinity constants. A higher displacer concentration results in higher product concentrations and shorter displacement time, but a longer regeneration time. A weaker displacer should be used to increase the effluent solute concentrations, shorten the cycle time and the regeneration time, and increase the feed volume. Therefore, the displacer affinity should be only slightly stronger than those of the solutes to obtain the highest productivity. The amount of displacer should also be minimized to the point that the displacer concentration in contact with the solutes is not significantly diluted at the time of breakthrough. This amount is usually a fraction of that required in common practice. The simulation results provide important guidelines for the optimal design of a displacement process." @default.
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- W2256650065 date "1989-01-01" @default.
- W2256650065 modified "2023-09-27" @default.
- W2256650065 title "Rate equation model simulation of displacement chromatography" @default.
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