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- W2257513809 abstract "Integral reaction cross sections as a function of initial translational energy (0.4--30 eV c.m.) are reported for isotopic variants of the exoergic ion- molecule reaction Ar$sup +$+CH$sub 4$ $Yields$ ArH$sup +$+CH$sub 3$. The excitation functions, which maximize at about 5 eV and decrease at lower collision energies, appear to possess translational energy thresholds at about 0.1 eV. At the higher energies there is a large isotope effect favoring abstraction of H over D. The observed threshold behavior, unusual for exoergic reactions of positive ions, is discussed in terms of the formation of an ArCH$sub 4$$sup +$ intermediate complex at low collision energies. (AIP)" @default.
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- W2257513809 date "1975-12-01" @default.
- W2257513809 modified "2023-09-23" @default.
- W2257513809 title "Excitation functions for the reactions of Ar$sup +$ with CH$sub 4$, CD$sub 4$, and CH$sub 2$D$sub 2$" @default.
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