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- W2257583254 abstract "The present work uses the concept of a scaled particle along with a perturbation approach for a multi-component fluid mixture, to develop an equation of state (EOS) for a hard sphere and Lennard-Jones fluid. A suitable flexible functional form for the radial distribution function G(R) is assumed for the liquid mixture, with the solute cavity R as a variable. The function G(R) is universal, in the sense that it is a common function for all the pairs, regardless of the composition and number of components of the mixture. The function G(R) has an arbitrary parameter m, where m is an arbitrary real number (pole) and the corresponding EOS is different for each value of m, i.e., m≈-1 leads to the Percus-Yevick (pressure), m=1 corresponds to the scaled-particle theory (SPT), and m=1/3 is close to the molecular dynamics (MD) result. As a special case of a liquid mixture, a comparison of the EOS at the critical temperature for a pure fluid of a hard-sphere and Lennard-Jones potential with molecular dynamics has also been done. A simple empirical correction allows us to obtain a highly accurate EOS with errors within those of the simulation." @default.
- W2257583254 created "2016-06-24" @default.
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- W2257583254 date "2011-10-01" @default.
- W2257583254 modified "2023-09-26" @default.
- W2257583254 title "Equation of State for a Hard-Sphere and Lennard-Jones Fluid Mixture" @default.
- W2257583254 hasPublicationYear "2011" @default.
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