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- W2257890306 abstract "The kinetic study of the anionic polymerization of isoprens is carried out in tetrahy-drofuran(THF), using n-BuLi as initiator. Kinetic parameters are obtained, which comprise chain propagation rate constant, kp, and partial rate constants, k3 and k4 +k5, propagstion orders with respect to monomer and active species concentration, α and β, real activation energy, E, as well as partial activation energies, E3 and E4+5 and so on. The relationship between the microstruc-ture of polyisoprene and the ratio of [THF]/[n-BuLi] has been investigated. On the basis of the studies mentioned above, a resonable mechanism of the anionic polynerization of isoprene is THF is proposed." @default.
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- W2257890306 date "1999-06-28" @default.
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- W2257890306 title "The Kinetic Study on the Anionic Polymerization of Isoprene" @default.
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