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- W2258191465 abstract "The impedance of a lithiumand manganese-rich layered transition-metal oxide (LMR-NMC) positive electrode, specifically Li1.2Ni0.15Mn0.55Co0.1O2, is compared to two other transition-metal layered oxide materials, specifically LiNi0.8Co0.15Al0.05O2 (NCA) and Li1.05(Ni1/3Co1/3Mn1/3)0.95O2 (NMC). A more detailed electrochemical impedance spectroscopy (EIS) study is conducted on the LMR-NMC electrode, which includes a range of states-of-charge (SOCs) for both current directions (i.e. charge and discharge) and two relaxation times (i.e. hours and one hundred hours) before the EIS sweep. The LMR-NMC electrode EIS studies are supported by half-cell constant current and galvanostatic intermittent titration technique (GITT) studies. Two types of electrochemical models are utilized to examine the results. The first type is a lithium ion cell electrochemical model for intercalation active material electrodes that includes a complex active material/electrolyte interfacial structure. The other is a lithium ion half-cell electrochemical model that focuses on the unique composite structure of the bulk LMR-NMC materials. © 2015 The Electrochemical Society. [DOI: 10.1149/2.0231504jes] All rights reserved." @default.
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- W2258191465 date "2015-01-01" @default.
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- W2258191465 title "Electrochemical Modeling and Performance of a Lithium- and Manganese-Rich Layered Transition-Metal Oxide Positive Electrode" @default.
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