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• W2258794651 abstract "This paper reports a novel method for identification of two aliphatic position isomers between α-ketoglutaric acid (α-KA) and β-ketoglutaric acid (β-KA) by their different perturbation effects on a Briggs–Rauscher oscillating system, in which tetraaza-macrocyclic complex [NiL](ClO4)2 is used as the catalyst. The ligand L in the complex is 5,7,7,12,14,14-hexamethyl-1,4,8,11-tetraazacyclotetradeca-4,11-diene. The experimental results have shown that addition of α-KA into the system does not affect the oscillating patterns, while the presence of β-KA in a dynamic system influences the oscillatory amplitude. A more interesting feature is that, in the presence of a higher concentration of β-KA, there are damped oscillations after the initial spike, followed by quenching (more exactly: very small oscillations) of the oscillations before the subsequent regeneration of oscillations. A qualitative approach was thus established by employing a Briggs–Rauscher system for identification of these two isomers. The concentrations of these two isomers that can be distinguished lie over the range between 5.0 × 10–6 and 2.5 × 10–3 mol/L. A reaction mechanism based on the FCA model has been proposed. An explanation is that β-KA reacts with HOO• radicals to form acetone, whereas the α-KA does not." @default.
• W2258794651 created "2016-06-24" @default.
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• W2258794651 date "2015-09-09" @default.
• W2258794651 modified "2023-10-18" @default.
• W2258794651 title "Identification of Two Aliphatic Position Isomers between α- and β-Ketoglutaric Acid by Using a Briggs–Rauscher Oscillating System" @default.
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• W2258794651 doi "https://doi.org/10.1021/acs.analchem.5b02649" @default.
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