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- W2259261363 abstract "The desorption performances of naphthalene and pyrene on mesoporous MCM-41, SBA-15, and CMK-3 sorbents are studied on the basis of temperature-programmed desorption experiments over the temperature range of 350–800 K at different heating rates. The kinetic parameters for each sorbate–sorbent pair are determined with combined model-fitting methods. The data for naphthalene and pyrene are best fitted with the same kinetic models on MCM-41 (with 1D mesopore channels), in contrast to those on SBA-15 and CMK-3, which have micropore–mesopore structures, leading to different desorption mechanisms for these two sorbates. SBA-15 with interconnectivity between adjacent mesopores not only shows high sorption capacities but also offers diffusion advantages in desorption, which contributes to the order of the degree of ease in desorption: SBA-15 > MCM-41 > CMK-3. CMK-3, with higher microporosity and hydrophobicity, shows stronger binding with the adsorbates while still benefiting in pyrene desorption from the consecut..." @default.
- W2259261363 created "2016-06-24" @default.
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- W2259261363 date "2016-01-26" @default.
- W2259261363 modified "2023-09-25" @default.
- W2259261363 title "Desorption of Polycyclic Aromatic Hydrocarbons on Mesoporous Sorbents: Thermogravimetric Experiments and Kinetics Study" @default.
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- W2259261363 doi "https://doi.org/10.1021/acs.iecr.5b03788" @default.
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