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• W2259285412 abstract "Abstract Rutile TiO 2 nanowhiskers with [0 0 1] growth direction were successfully fabricated by treating bulk Ti 3 Si 0.9 Al 0.1 C 2 solid solution at 900 °C in 10 4  Pa air. In the initial stage, TiO 2 nanowhiskers are preferentially formed on the side facets of Ti 3 Si 0.9 Al 0.1 C 2 grains due to the rapid diffusion of Ti atoms along the basal planes. With the increase of treating time, a mixed oxide scale of TiO 2 , SiO 2 and Al 2 O 3 is gradually developed. Consequently, the growth of TiO 2 nanowhiskers is controlled by the diffusion of Ti in the mixed oxide scale. In addition, it is found that the growth rate of TiO 2 nanowhiskers strongly depends on the air pressure and the treating temperature. It diminishes dramatically with the decrease of temperature. However, only TiO 2 nanosheets and large grains can be obtained above 1000 °C. In addition, air pressure around 10 4  Pa is appropriate for the growth of nanowhiskers." @default.
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• W2259285412 date "2016-05-01" @default.
• W2259285412 modified "2023-09-27" @default.
• W2259285412 title "Fabrication of TiO 2 nanowhiskers by the heat treatment of bulk Ti 3 Si 0.9 Al 0.1 C 2 in rough vacuum" @default.
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• W2259285412 doi "https://doi.org/10.1016/j.ceramint.2016.01.070" @default.
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