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- W2259314958 abstract "Publisher Summary The chapter discusses the biochemistry of pseudouridine. It also discusses in a critical, selective, and occasionally speculative fashion, the special enzymological properties, the mode of biosynthesis, and the biological role of pseudouridine. Pseudouridine and its phosphorylated derivatives form a class of biochemically distinctive compounds. In some cases, these compounds appear to participate in enzymatic reactions, as analogs of uridine and its phosphate esters, but there are reactions, in which the 5-ribosyl bond confers a degree of specificity. Several proposed mechanisms for the biosynthesis of polynucleotide ψ have been discussed in this chapter. These include a pathway via diribosyluracil, an intramolecular rearrangement, and the direct condensation of uracil and ribose 5-phosphate to yield ψ monophosphate (MP). While the last reaction occurs in at least two organisms, the data available at present is insufficient to exclude completely any of the three proposals. The most probable pathway of the formation of polynucleotide ψ is by way of the direct incorporation of ψ triphosphate (TP) formed from ψ MP, arising by direct condensation." @default.
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- W2259314958 date "1966-01-01" @default.
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- W2259314958 title "The Biochemistry of Pseudouridine" @default.
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- W2259314958 doi "https://doi.org/10.1016/s0079-6603(08)60241-x" @default.
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