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• W2259426167 abstract "The title compound, poly[( μ 3 -formato)( μ 4 -oxalato)terbium(III)], [Tb(CHO 2 )(C 2 O 4 )] n , is a three-dimensional coordination polymer, and is isotypic with the La III , Ce III and Sm III analogues. The asymmetric unit contains one Tb III ion, one formate anion (CHO 2 − ) and half of an oxalate anion (C 2 O 4 2− ), the latter being completed by application of inversion symmetry. The Tb III ion is nine-coordinated in a distorted tricapped trigonal–prismatic manner by two chelating carboxylate groups from two C 2 O 4 2− ligands, two carboxylate oxygen atoms from another two C 2 O 4 2− ligands and three oxygen atoms from three CHO 2 − ligands, with the Tb—O bond lengths and the O—Tb—O bond angles ranging from 2.4165 (19) to 2.478 (3) Å and 64.53 (6) to 144.49 (4)°, respectively. The CHO 2 − and C 2 O 4 2− anions adopt μ 3 -bridging and μ 4 -chelating-bridging coordination modes, respectively, linking adjacent Tb III ions into a three-dimensional 12-connected fcu topology with point symbol (3 24 .4 36 .5 6 ). The title compound exhibits thermal stability up to 623 K, and also displays strong green photoluminescence in the solid state at room temperature." @default.
• W2259426167 created "2016-06-24" @default.
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• W2259426167 date "2016-01-01" @default.
• W2259426167 modified "2023-10-01" @default.
• W2259426167 title "Crystal structure of a mixed-ligand terbium(III) coordination polymer containing oxalate and formate ligands, having a three-dimensional fcu topology" @default.
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• W2259426167 doi "https://doi.org/10.1107/s205698901502397x" @default.
• W2259426167 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/4704756" @default.
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