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- W2259666085 abstract "A transition metal-free, chemoselective reaction was performed using the sodium tert-butoxide-oxygen (NaO(t) Bu-O2 ) system, resulting in either oxidative dehomologation or direct oxidation of alcohols. In particular, the newly developed protocol may be used to predict the major product formed, which depends on alkyl chain length of the alcohols and reaction conditions. The rational mechanism of this transformation was also demonstrated by performing an (18) O isotopic labelling experiment. This protocol presents a straightforward method for biomass conversion of a lignin model compound to phenol and benzoic acid." @default.
- W2259666085 created "2016-06-24" @default.
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- W2259666085 date "2015-12-18" @default.
- W2259666085 modified "2023-10-17" @default.
- W2259666085 title "Metal-Free Chemoselective Oxidative Dehomologation or Direct Oxidation of Alcohols: Implication for Biomass Conversion" @default.
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- W2259666085 doi "https://doi.org/10.1002/cssc.201501359" @default.
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