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- W2260659829 abstract "在低温下利用配合物电子吸收光谱强度与时间的相关性, 研究了双核铁(Ⅱ)配合物[Fe 2 (N-Et- HPTB){O 2 P(OPh) 2 }](ClO 4 ) 2 ( 1 )和[Fe 2 (N-Et-HPTB){O 2 P(Ph) 2 }](ClO 4 ) 2 ( 2 )与分子氧反应生成过氧化物桥联的双核三价铁过渡态配合物在不同的温度下分解反应的动力学性质. 在实验条件下, 分子氧加合物的分解反应为一级反应, 并利用Eyring方程得到了分子氧加合物分解反应相应的活化参数. 对于 1 /O 2 来说, Δ H ¹ = 85.62 kJ·mol -1 , Δ S ¹ = 19.43 J·mol -1 ·K -1 ; 对于 2 /O 2 来说, Δ H ¹ = 97.97 kJ·mol -1 , Δ S ¹ = 55.68 J·mol -1 ·K -1 . 这一结果与其他分子氧加合物以及天然酶(MMOH)中O—O键断裂的活化参数值相当." @default.
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- W2260659829 date "2001-12-15" @default.
- W2260659829 modified "2023-09-24" @default.
- W2260659829 title "双核铁(II)/O 2 加合物分解反应动力学" @default.
- W2260659829 hasPublicationYear "2001" @default.
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