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• W2260894736 startingPage "9038" @default.
• W2260894736 abstract "The effect of C2–H of alkylimidazolium tetrafluoroborate ionic liquids on the interaction and vapor–liquid equilibrium (VLE) of the ethyl acetate + ethanol mixture was studied using spectroscopy and the COSMO-RS method. Concentration-dependent 1H NMR chemical shifts of ethyl acetate + ethanol + [Bmim]BF4 or [Bmmim]BF4 (xIL = 0.1 and 0.3) systems show that the interaction between [Bmim]BF4 and ethanol is much stronger than that between [Bmmim]BF4 and ethanol. Moreover, the experimental and predicted VLE demonstrate that the improvement of relative volatility of ethyl acetate to ethanol by [Bmim]BF4 is better than that by [Bmmim]BF4. Also, σ-profile obtained from COSMO-RS method indicates that the hydrogen bonding donator ability of [Bmim]+ is greater than that of [Bmmim]+. Therefore, it can be deduced that the acidic C2–H plays an important role in the interaction differentiation of the ionic liquids and their effect on the VLE of the ethyl acetate + ethanol system, resulting from the interaction of the acidic C2–H with the ethanol that is much stronger than with the ethyl acetate." @default.
• W2260894736 created "2016-06-24" @default.
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• W2260894736 date "2015-08-31" @default.
• W2260894736 modified "2023-10-10" @default.
• W2260894736 title "Influence of C2–H of Imidazolium-Based Ionic Liquids on the Interaction and Vapor–Liquid Equilibrium of Ethyl Acetate + Ethanol System: [Bmim]BF₄ vs [Bmmim]BF₄" @default.
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• W2260894736 doi "https://doi.org/10.1021/acs.iecr.5b01325" @default.
• W2260894736 hasPublicationYear "2015" @default.
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