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• W2262569651 abstract "Porous Ti5Si3 and Ti5Si3/TiAl intermetallics were fabricated by self-propagating high-temperature synthesis (SHS) from elemental powder compacts with addition of TiH2. The TiH2 content ranged from 1.25 to 6.25 mol.% for formation of the Ti5Si3 monoliths and from 2 to 10 mol.% for the Ti5Si3/TiAl composites. Due to endothermic decomposition of TiH2, the increase of TiH2 decreased the reaction temperature and combustion wave velocity. Moreover, dehydrogenation of TiH2 released hydrogen gas to act as a pore-forming agent and generated highly reactive Ti to facilitate the reaction. The porosity of the intermetallic product increased with increasing TiH2 content and the microstructure with a uniform distribution of pores was attained. As a consequence, the porosity of as-synthesized Ti5Si3 monoliths was controllable and increased from 38% to 60% with TiH2 additions. Likewise, Ti5Si3/TiAl composites with an increasing porosity from 31% to 56% were obtained from the TiH2-added samples." @default.
• W2262569651 created "2016-06-24" @default.
• W2262569651 creator A5005646755 @default.
• W2262569651 creator A5045199866 @default.
• W2262569651 date "2016-06-01" @default.
• W2262569651 modified "2023-10-15" @default.
• W2262569651 title "Use of TiH2 as a reactant in combustion synthesis of porous Ti5Si3 and Ti5Si3/TiAl intermetallics" @default.
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• W2262569651 doi "https://doi.org/10.1016/j.jallcom.2016.01.236" @default.
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